About Polaris
Polaris is the software operating with the new modified line of CM-3600
series of instruments from Minolta, especially modified for measuring white samples containing Fluorescent Whitening Agents (FWA). The software takes full advantage of the use of more than one flash-lamp with the
CM-3600 instruments to handle fluorescence and absorption separately; the calculation final colorimetric data takes into consideration the mixing of additive and subtractive parts of the detected fluorescent color. Polaris is a program specifically made for whiteness measurements with following functions:
- measurement of reflectance spectra of white fluorescent samples
- calculation of non-fluorescent and fluorescent contributions to reflectance
- calculation of colorimetric data under consideration of additive and substrative color mixing
- calculation of whiteness-related values as total numbers and as contributions from base white, shading and fluorescent parts
- calculation of whiteness-related values under different illuminants to assess metameric effects
- graphical spectral presentation and printable tables of results
- storage of results in Access databank
Further features are: Starting with version 1.3
- calculation module for scattering and absorption factors
- tools for selection and recipe formulation for substrates fillers (paper area)
Starting with version 1.4:
- tools for selection and recipe formulation for substrates and shading agents (all areas)
Starting with version 1.5:
- tools for selection and recipe formulation for fluorescent whitening agents (all areas)
General features
The instrument provides data in the range of 360 to 740 nm, depending on the model also in two sets as
Specular Included (SCI) and Specular Excluded (SCE) conditions.
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Model
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CM-3600 and CM-3610
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CM-3630
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Wavelength range
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360-740 nm
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360-740 nm
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Aperture
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LAV, MAV, SAV
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33 mm diam.
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Specular components
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SCE / SCI
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SCE
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Reflectance data is used to calculate main colorimetric data as indicated in the following table:
Illuminants
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Observers
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Daylight
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D50,D55,D65, D75
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CIE-1931
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2°
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Incandescent (2856 °K)
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A
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CIE-1964
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10°
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Fluorescent light sources
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TL-84, F6 and F11
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ASTM-308
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2° and 10°
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Artificial daylight
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C
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Colorimetric data
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Color difference formulas
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Tristimulus values
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(X, Y, Z)
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Euclidean (L*a*b*)
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DELab
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Chromaticity coordinates
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(x,y)
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Euclidean (L*c*h*)
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DELch
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CIE uniform color coordinates
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(L*,a*,b*)
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After CIE-94
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DE94
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After CMC
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DECMC
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After DIN-99
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DEDIN99
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After CIE-DE 2000
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DECIEDE2000
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Whiteness indices
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Opacity
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After CIE
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WICIE, TintCIE
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ASTM D-589
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C0.89
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After Ganz
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WIGanz, TintGanz-Griesser
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TAPPI T-519/ ISO 2471
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On
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After Berger
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WIBerger
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Normalized TAPPI
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Cn
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After ASTM
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WIASTM
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Paper brightness
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Yellowness index
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TAPPI T-525/ ISO 2470
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BISO
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After ASTM
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YIASTM
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In addition to these quantities several other, area-specific ones are calculated and shown depending on the application. The latter can be chosen
among Paper, Recycled paper, Textiles, Detergents, Paints, Liquids and Glass.
Calculation modes
Main characteristic of Polaris is the separation of absorptive and fluorescent parts of the light coming from the instrument. In the case of fluorescent
white samples, fluorescence is separated from absorption and data is calculated according to the formula:
where
K
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= X, Y, Z
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Sl
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= Illuminant
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Rl(a)
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= Reflectance (absorptive part)
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Rl(f)
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= Reflectance (fluorescence part)
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kl
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= xl, yl, zl tristimulus function
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Rl(f) is corrected for distortions from the lamp energy distribution; this correction improves the accuracy of results and leads to an independence of
measured values on individual instruments. As a further consequence calculated tint values also agree among the different instruments.
Results are expressed still based on normed whiteness values but the pictorial
representation changes (see picture right) is shown as a result of the separation of fluorescent and non-fluorescent parts. Base white can be assessed fully even in those
regions until now inaccessible i.e. below 420 or 400 nm. The information gained from this region of the spectrum is vital for assessing the efficiency of the FWA.
Fluorescence separation is set on refelctance data through a calibration using conventional polyester fluorescent standards (from Textilforschungsinstitut Thüringen-Vogtland, Germany
); instruments are delivered precalibrated such that they can be used readily after installation. The user must decide which whiteness standard to use for daylight conditions among the
standard available on the market; other illuminants (C, A and TF-84) are referred to this calibration and do not need additional calibration; the possibility to calculate color data with
more than one illuminant allows the assessment of metameric effects of measured whiteness. Shading agents are taken into account by converting the absorption part into (k/s) values
and fitting the background to model substrates to obtain the absorption profile of the dye. The separation of the three contributions allows the calculation and study of the different
phenomena that results into a particular whiteness perception; furthermore this knowledge can be applied for controlling given levels of whiteness or for guiding lab experiments
towards conditions needed to achieve them.
System requirements
- Personal computer Pentium IV or higher with RCS-232 port
- Operating system Windows NT(SP5)/2000/XP
- CD ROM reader unit
- Hard-disk with 20 MB free space (program and working environment)
System components
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